Liverpool booked their spot in the next stage by beating Tottenham Hotspur 3-1 in their round-three clash at Anfield on Tuesday.
The Reds will find out their next opponents when the draw takes place live on Sky Sports following the conclusion of the tie between Manchester United and Brighton & Hove Albion on Wednesday.
They will be ball number eight.
Fourth-round games are scheduled to be played in the week commencing October 26.