The striker is handed a Reds debut for the fixture at Anfield after completing his deadline-day transfer to the champions earlier this month.
Elsewhere, Arne Slot makes two further changes from the weekend win at Burnley, with Jeremie Frimpong and Andy Robertson coming back into the XI.
Liverpool: Alisson, Van Dijk, Konate, Wirtz, Szoboszlai, Isak, Salah, Gakpo, Robertson, Frimpong, Gravenberch.
Subs: Mamardashvili, Woodman, Gomez, Endo, Kerkez, Mac Allister, Bradley, Leoni, Ekitike, Danns, Ngumoha.
