A restructured format for the tournament will see the Reds play six games during the first stage, three at home and three away.
All 23 participating teams will be ranked in an overall league table and the top eight finishers advance to the knockout rounds.
In the league phase, Liverpool are set to face Sunderland, Birmingham City, Manchester United, Aston Villa, Nottingham Forest and Burnley.
Subway Players Cup fixtures
Dates and kick-off times subject to change
September 23 (7pm) – Liverpool v Sunderland
September 30 (7pm) – Birmingham City v Liverpool
October 21 (7pm) – Liverpool v Manchester United
November 11 (7pm) – Liverpool v Aston Villa
November 18 (7pm) – Nottingham Forest v Liverpool
December 16 (7pm) – Burnley v Liverpool
